Selective recovery of gold and silver from electronic wastes through a sequential process of Qalkari and room-temperature hydrometallurgy.

This work was focused on the selective recovery of gold and silver from electronic wastes using a sequential process of pyrometallurgy (Qalkari) and room-temperature hydrometallurgy. In the first step, electronic wastes underwent Qalkari recycling, yielding tablets containing precious elements (Qalkari furnace product) and melting slag (Qalkari furnace waste). In the subsequent hydrometallurgy phase, the nitric acid concentration and the input solid amount were optimized for the effective room-temperature recovery of gold. Due to the successful separation of precision elements and disturbing substances in Qalkari, the gold recovery efficiency of 99.99% was obtained at the acid concentration of 50% (v/v) and the solid input of 15% (w/v). Afterwards, HCl, NH4Cl, and NaCl were used for silver recovery from the Qalkari-processed gold-recovered leaching solution, leading to the efficiency of 99.99%. But NH4Cl was recognized as the most effective precipitant as it promises the most enhanced potential for the possible subsequent recovery of palladium. In conclusion, this study draws the effectiveness of Qalkari in recycling electronic wastes, with a significant impact on the efficiency of succeeding room-temperature hydrometallurgical processes for gold and silver recovery within a reasonable leaching time.

MIL-161 Metal-Organic Framework for Efficient Au(III) Recovery from Secondary Resources: Performance, Mechanism, and DFT Calculations.

The recovery of precious metals from secondary resources is significant economically and environmentally. However, their separation is still challenging because they often occur in complex metal ion mixtures. The poor selectivity of adsorbents for gold in complicated solutions prevents further application of adsorption technology. In this study, a Zr-based MOF adsorbent, MIL-161, was synthesized using s-tetrazine dicarboxylic acid (H2STz) as an organic ligand. MIL-161 demonstrated a high adsorption capacity of up to 446.49 mg/g and outstanding selectivity for gold(III) in a simulated electronic waste solution as a result of the presence of sulfur- and nitrogen-containing groups. In addition, the MIL-161 adsorbents were characterized using Fourier transform infrared (FT-IR), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TG), Brunner-Emment-Teller (BET), and X-ray photoelectron spectroscopy (XPS). Additionally, the adsorption kinetics, isotherms, and thermodynamics of the MOF adsorbents were also thoroughly examined. More importantly, the experimental results and DFT calculations indicate that chelation and electrostatic interactions are the main adsorption mechanisms.

A critical review of the pre-processing and metals recovery methods from e-wastes.

E-wastes being potential sources of numerous valuable metals are promoted to undergo recycling and recovery under the umbrella of urban mining and circular economy. Thus, the present study provides a critical review of the technological details of different metal recycling processes, pre-treatment methods, and the advancements made in these techniques. Critical evaluation of different metal recovery techniques has also been presented based on the available life cycle assessment (LCA), techno-economic, and industrial-scale studies. The study revealed that the integrated metal recovery techniques serve better in terms of recovery efficiency and environmental performance than any single recovery technique. Also, scaling up of biometallurgical, electrochemical, and super critical fluid extraction methods needs to be promoted due to their better environmental performances.

Static and dynamic studies of lanthanum(III) ion adsorption/desorption from acidic solutions using chelating ion exchangers with different functionalities.

Increasing the number of applications of rare earth elements (REEs) has led to increased release of these metals into the environment. Removal of REEs from e-wastes is very important considering the increasing demand for these elements, the limited resource availability of them as well as the significant environmental issues. In this present study, optimization of the La(III) ions sorption from acidic solutions on chelating ion exchangers containing different functional groups, i.e. Amberlite IRC748, Purolite S930, Lewatit® Monoplus TP208, Amberlite IRC747, Purolite S940, and Purolite S950, was carried out. The sorption data was analyzed using the Lagergren pseudo-first order, Ho and McKay pseudo-second order, Weber-Morris intraparticle diffusion, Boyd kinetic models, pore and film diffusion coefficients as well as the Langmuir, Freundlich, and Temkin isotherm models. Additionally, thermodynamic parameters and regeneration abilities of chelating ion exchangers were evaluated. The maximum recovery of La(III) ions was found for HNO3 concentration equal to 0.2 mol/dm3. The La(III) ions sorption was fast and sorption equilibrium was achieved after about 60 min. The best fitting for the lanthanum(III) ions sorption was obtained using the pseudo-second order kinetic and Langmuir isotherm models. Moreover, breakthrough curves were obtained from dynamic studies. The physicochemical characterization places special emphasis on determination of chemical composition of ion exchangers using ATR/FT-IR and XPS spectroscopy. Furthermore, characterization parameters of ion exchangers such as surface area and porosity (pore size), point of zero charge, and thermal stability were estimated. Chelating ion exchangers with aminophosphonic functional groups are characterized by the best adsorption properties towards La(III) ions so they could be used for the recovery of rare earth elements from spent battery solutions.

Environmental and economic performance analysis of recycling waste printed circuit boards using life cycle assessment.

Recycling precious elements from the electronic waste could be an environmental friendly way to avoid likely ecological damages caused by leaching of heavy metals and toxic elements as well as an economically attractive option to recover valuable materials that would otherwise be wasted. This research assessed the environmental and economic performance of recovering nine metal elements (aluminum (Al), copper (Cu), gold (Au), lead (Pb), nickel (Ni), silver (Ag), tin (Sn), zinc (Zn), and iron (Fe)) and two non-metal materials (resin and glass-fiber) from the waste printed circuit boards (PCBs), one of the vital components of electronic-waste (e-waste). SimaPro software was used to assess the environmental performance of recycling waste PCBs. Data were collected from recycling plants in Taichung City, Taiwan, and Eco-invent database was also used in the study. The impacts of metal recycling from PCBs were compared with the impacts caused by the mining of respective metals from their natural ores. Among the analyzed elements, only the recovery of Au from waste PCBs proved to have less environmental impacts than the mining from the natural ore. Among 16 environmental impact categories (ILCD midpoint 2011+ method of impact analysis) considered in the present study, cancer and non-cancer human toxicity were the most affected categories followed by minerals, fossils, and resource extraction. However, the economic analysis showed that the recycling of all elements from waste PCBs had a net positive benefit. When considering both the environment and economic performance, the recycling of Au proved to be a beneficial option.

Chemical pyrolysis of E-waste plastics: Char characterization.

This work studied the disposal of the non-metallic fraction from waste printed circuit board (NMF-WPCB) via the chemical pretreatments followed by pyrolysis. As a main heavy metal, the metallic Cu could be significantly removed by 92.4% using the HCl leaching process. Subsequently, the organic-Br in the brominated flame retardants (BFRs) plastics could be converted into HBr by pyrolysis. The alkali pretreatment was benefit for the Br fixation in the solid char. The Br fixation efficiency could reach up to 53.6% by the NaOH pretreatment followed by the pyrolysis process. The formed HBr could react with NaOH/KOH to generate the stabilized NaBr/KBr. Therefore, the integrated chemical pretreatment could be used for the eco-friendly disposal of the NMF-WPCB via pyrolysis.

Recent developments and perspective of the spent waste printed circuit boards.

The amount of spent electronic and electrical solid wastes (i.e. e-wastes) has increased to a new level with the rapid development of electronic and electrical industries. Management of e-wastes challenges the administrators and researchers. As a major component of the e-waste stream, pollution caused by the spent printed circuit boards has captured increasing attention. Various innovative methods have recently been developed to dispose and reuse these municipal spent printed circuit boards. In this mini-review article, the disposal approaches for spent printed circuit boards are highlighted. The present state and future perspective are also discussed. We hope that this mini-review can promote the extensive understanding and effective disposal of the spent printed circuit boards in the field of solid waste treatment and resources.

Assessment of heavy metals exposure, noise and thermal safety in the ambiance of a vacuum metallurgy separation system for recycling heavy metals from crushed e-wastes.

Vacuum metallurgy separation (VMS) is a technically feasible method to recover Pb, Cd and other heavy metals from crushed e-wastes. To further determine the environmental impacts and safety of this method, heavy metals exposure, noise and thermal safety in the ambiance of a vacuum metallurgy separation system are evaluated in this article. The mass concentrations of total suspended particulate (TSP) and PM10 are 0.1503 and 0.0973 mg m(-3) near the facilities. The concentrations of Pb, Cd and Sn in TSP samples are 0.0104, 0.1283 and 0.0961 µg m(-3), respectively. Health risk assessments show that the hazard index of Pb is 3.25 × 10(-1) and that of Cd is 1.09 × 10(-1). Carcinogenic risk of Cd through inhalation is 1.08 × 10(-5). The values of the hazard index and risk indicate that Pb and Cd will not cause non-cancerous effects or carcinogenic risk on workers. The noise sources are mainly the mechanical vacuum pump and the water cooling pump. Both of them have the noise levels below 80 dB (A). The thermal safety assessment shows that the temperatures of the vacuum metallurgy separation system surface are all below 303 K after adopting the circulated water cooling and heat insulation measures. This study provides the environmental information of the vacuum metallurgy separation system, which is of assistance to promote the industrialisation of vacuum metallurgy separation for recovering heavy metals from e-wastes.

Simultaneously enhanced Cu bioleaching from E-wastes and recovered Cu ions by direct current electric field in a bioelectrical reactor.

In this study, a proof-of-concept of bioleaching and recovery of copper (Cu) from E-wastes assisted by direct current (DC) electric field was proved in a bioelectrical reactor. Results showed that 40 mA electric current application could not only significantly shorten the leaching time of Cu from 5 (control) to 3 days with 100% leaching efficiency, but also recover about 97% leached Cu ions within 4 days. DC electric field improved the activity and growth of iron oxidizing bacteria and facilitated Fe2+ oxidation, which resulted in effective leaching of Cu from printed circuit boards (PCBs). The functional Acidithiobacillus was selectively enriched by DC electric field for enhancing the efficiency of bioleaching. At the same time, the leached Cu ions were rapidly electrodeposited on the cathode, achieving the recovery of Cu. Hence, this work provided a novel strategy for metals bioleaching and recovery from E-wastes.

Towards minimization of secondary wastes: Element recycling to achieve future complete resource recycling of electronic wastes.

Recycling resources from millions of tons of e-wastes are a global challenge. E-wastes is complex and contains both toxic organics and valuable metals. Therefore, the technologies for e-wastes recycling are totally different from those used for mineral separation. Current technologies for e-wastes tend to focus on recycling materials with high economic value and ignore components that cannot be recycled or have low reuse value. As a result, some secondary pollution problems inevitably occur due to the recycling process. Based on these problems, we summarize the universal characteristics of e-wastes and explore new approaches to achieve complete resource recycling of e-wastes with minimum secondary waste generation. A concept of element recycling is proposed to achieve complete resource recycling of e-wastes in the study. We can use the properties of the elements in different types of e-wastes to achieve e-wastes recycling, i.e., recycle of elements in e-wastes. Under the guidance of element recycling, various e-wastes types have common connections. If element recycling in e-wastes is realized, all components in e-wastes can be fully recycled without/with minimal production of secondary waste. The two case studies are discussed to clarify the concept and principle of element recycling. This study explores the recycling of e-wastes from a new perspective-element recycling in e-wastes. The concept of element recycling is significant for resource recycling from e-wastes.

Leaching of indium from end-of-life LCD panels via catalysis by synergistic microbial communities.

Currently, a large amount of discarded liquid crystal displays (LCDs) are being produced, and the improper treatment of discarded LCDs causes serious environmental pollution problems. Indium is the most valuable metal in LCDs and is present in such devices at a concentration of over 0.025%. In this study, the bioleaching of indium from end-of-life LCD panels was comprehensively investigated through three methods: S-mediated pathway, Fe-mediated pathway and Mixed pathway of S- and Fe-mediated, which yielded maximum bioleaching efficiencies of approximately 100%, 0% and 78%, respectively. Microbial community analysis showed that the dominant functional bacteria under the S-mediated pathway were Acidithiobacillus. The Acidithiobacillus genus catalysed the leaching of indium, which was mainly achieved by indirect bioleaching. In addition, the microorganisms can secrete enzymes and extracellular polymeric substances, which also contributed to the leaching of indium. Therefore, this work provides an economical and efficient biological method for future research and practical applications in indium recovery from solid waste.

Emission behaviors of nitro- and oxy-polycyclic aromatic hydrocarbons during pyrolytic disposal of electronic wastes.

Emission factors (EFs) of polycyclic aromatic hydrocarbon (PAH) derivatives (12 nitro-PAHs and 4 oxy-PAHs) during the pyrolysis of two types of electronic waste (E-waste) were measured. Compositional profile, particle size distribution, gas-particle partitioning, correlations with precursor species and influences of pyrolytic temperature were investigated. The derivative products were dominated by oxy-PAHs. The averaged EFs of oxy-PAHs were 3.37 ±â€¯4.10 µg/g and 32.6 ±â€¯18.1 µg/g for PWBs and plastic casings, respectively, and those of nitro-PAHs were 85.7 ±â€¯92.4 ng/g and 83.3 ±â€¯69.7 ng/g, respectively. Most EFs of derivative species significantly correlated with their corresponding parent PAHs (p < 0.05), except a few cases, indicating formation of derivatives via related reactions of parent species. Most nitro-PAHs occurred in fine particles with the size < 2.1 µm, and oxy-PAHs were prevailing in fine particles with the size between 0.4 µm and 2.1 µm. Proportions of oxy-PAHs in particulate phase, especially those with higher molecular weight, were noticeably greater than those of the corresponding parent species. Below 480 °C, there was no evident difference in the EFs of PAH derivatives, while the EFs noticeably increased from 520 °C. With the increasing temperature, the majority of oxy-PAHs still occurred on finer particles, while the contribution of coarser particles tended to increase.

Emission characteristics of polycyclic aromatic hydrocarbons from pyrolytic processing during dismantling of electronic wastes.

Two typical types of electronic waste (E-waste) were selected to investigate the emission characteristics of polycyclic aromatic hydrocarbons (PAHs) during pyrolytic processing, including emission factor, compositional profile, size distribution and gas-particle partitioning. The mean emission factors (EFs) of total PAHs were measured to be 2.77 ±â€¯1.41 µg/g and 23.65 ±â€¯14.52 µg/g for printed wiring boards and plastic casings, respectively, lower than those for coal combustion and biomass burning. Low molecular weight species were predominant in exhaust fumes, with overwhelming amounts of naphthalene (NAP) and phenanthrene (PHE) in the gaseous phase and particulate phase, respectively. The particle-size distribution exhibited the largest enrichment of total PAHs in finer particles less than 2.1 µm. Similarly, the distributions of individual species were dominated by finer particles. Most freshly emitted PAHs were liable to exist in particulate phase relative to gaseous phase. Based on the benzo[a]pyrene equivalent carcinogenic power, PAHs in particulate phase may have much stronger toxicity compared with those present in gaseous phase. The gas-particle partitioning behaviors of freshly emitted PAHs from pyrolytic processing of E-wastes were mainly regulated by absorption rather than adsorption, and the gas-particle partitioning did not reach equilibrium.

PBDE emission from E-wastes during the pyrolytic process: Emission factor, compositional profile, size distribution, and gas-particle partitioning.

Polybrominated diphenyl ether (PBDE) pollution in E-waste recycling areas has garnered great concern by scientists, the government and the public. In the current study, two typical kinds of E-wastes (printed wiring boards and plastic casings of household or office appliances) were selected to investigate the emission behaviors of individual PBDEs during the pyrolysis process. Emission factors (EFs), compositional profile, particle size distribution and gas-particle partitioning of PBDEs were explored. The mean EF values of the total PBDEs were determined at 8.1 ±â€¯4.6 µg/g and 10.4 ±â€¯11.3 µg/g for printed wiring boards and plastic casings, respectively. Significantly positive correlations were observed between EFs and original addition contents of PBDEs. BDE209 was the most abundant in the E-waste materials, while lowly brominated and highly brominated components (excluding BDE209) were predominant in the exhaust fumes. The distribution of total PBDEs on different particle sizes was characterized by a concentration of finer particles with an aerodynamic diameter between 0.4 µm and 2.1 µm and followed by less than 0.4 µm. Similarly, the distribution of individual species was dominated by finer particles. Most of the freshly emitted PBDEs (via pyrolysis) were liable to exist in the particulate phase with respect to the gaseous phase, particularly for finer particles. In addition, a linear relationship between the partitioning coefficient (KP) and the subcooled liquid vapor pressure (PL0) of the different components indicated non-equilibrium gas-particle partitioning during the pyrolysis process and suggested that absorption by particulate organic carbon, rather than surface adsorption, governed gas-particle partitioning.

Source characterization and risk of exposure to atmospheric polychlorinated biphenyls (PCBs) in Ghana.

With recent evidence that persistent organic pollutants (POPs) such as polychlorinated biphenyls (PCBs) are emerging in environmental media in some developing countries that otherwise have sparing production and usage history, it has become important to identify such contemporary source factors of PCBs and the risks this may pose, in line with the global consensus on POP management and elimination. The present study investigated contaminations from atmospheric PCBs in Ghana, deciphered source factors, and accessed risk of exposure to dioxin-like PCBs (DL-PCBs). Atmospheric PCBs were monitored by deployment of PUF-disk passive air samplers (PAS) at several sites across Ghana for 56 days. Atmospheric ∑190PCB concentration in Ghana ranged from 0.28 ng/m3 in Kumasi to 4.64 ng/m3 at Agbogbloshie, a suburb in Accra noted for informal electronic waste (e-waste) recycling activities. As high as 11.10 ng/m3 of PCB concentration was measured in plumes from uncontrolled open burning of e-wastes at Agbogbloshie. Applying statistical source characterization tools, it emerged that e-wastes were a major contributor to the environmental burden of atmospheric PCBs in Ghana. The risk of DL-PCB toxicity via inhalation in the Agbogbloshie area was 4.2 pg TEQ/day, within similar order of magnitude of an estimated risk of 3.85 pg TEQ/day faced by e-waste workers working averagely for 8 h per day. It is suggested that elimination of e-waste sites would help to significantly reduce PCB-related toxicity issues in Ghana. Graphical abstract ᅟ.

Enhanced bioleaching efficiency of metals from E-wastes driven by biochar.

Electronic wastes (E-wastes) contain a huge amount of valuable metals that are worth recovering. Bioleaching has attracted widespread attention as an environment-friendly and low-cost technology for the recycling of E-wastes. To avoid the disadvantages of being time-consuming or having a relatively low efficiency, biochar with redox activity was used to enhance bioleaching efficiency of metals from a basic E-waste (i.e., printed circuit boards in this study). The role of biochar was examined through three basic processes: Carbon-mediated, Sulfur-mediated and Iron-mediated bioleaching pathways. Although no obvious enhancement of bioleaching performance was observed in the C-mediated and S-mediated systems, Fe-mediated bioleaching was significantly promoted by the participation of biochar, and its leaching time was decreased by one-third compared with that of a biochar-free system. By mapping the dynamic concentration of Fe(II) and Cu(II), biochar was proved to facilitate the redox action between Fe(II) to Fe(III), which resulted in effective leaching of Cu. Two dominant functional species consisting of Alicyclobacillus spp. and Sulfobacillus spp. may cooperate in the Fe-mediated bioleaching system, and the ratio of these two species was regulated by biochar for enhancing the efficiency of bioleaching. Hence, this work provides a method to improve bioleaching efficiency with low-cost solid redox media.

Spatial characteristics of cadmium in topsoils in a typical e-waste recycling area in southeast China and its potential threat to shallow groundwater.

Informal electrical and electronic waste (e-waste) recycling often creates secondary sources of cadmium (Cd) pollution. To characterize the total Cd concentration (Cdtotal) in topsoil and evaluate the threat of Cd in topsoils to shallow groundwater, 187 topsoil samples and 12 shallow groundwater samples were collected in a typical e-waste recycling area in southeast China. Soil organic matter content, soil pH and Cdtotal in topsoil, pH and dissolved Cd concentration in shallow groundwater were measured. Cdtotal in the topsoils showed an inverse distribution trend with soil pH in that high Cd concentrations (and low pH values) were found in the surrounding area of the metal recycling industrial park where there were many family-operated e-waste recycling facilities before the industrial park was established and with low concentrations (and high pH values) in other areas, and they had similar spatial correlation structures. Cd accumulation and acidification were synchronous in topsoils, and soil pH was significantly correlated with Cdtotal in topsoils with low to moderate negative correlation coefficient (r=-0.24), indicating that both of them maybe correlated with informal recycling. The shallow groundwater in the surrounding area of the metal recycling industrial park was seriously contaminated by Cd, and topsoil Cd accumulation and acidification in the surrounding area of e-waste recycling sites significantly increase the risk of shallow groundwater contaminated by Cd. Action is urgently required to control Cd accumulation and acidification by improving the recycling operations of e-wastes in order to reduce the risk of Cd leaching from topsoils and shallow groundwater contamination.