RESUMO
The use of chemical pesticides in agriculture contributes to soil, water and air pollution, biodiversity loss, and injury to non-target species. The European Commission has already established a Harmonized Risk Indicator to quantify the progress in reducing the risks linked to pesticides. Therefore, there is an increasing need to promote biopesticides, or so-called low-risk pesticides (LRP). Tea tree oil (TTO) is known for its antiseptic, antimicrobial, antiviral, antifungal, and anti-inflammatory properties. TTO has been extensively studied in pest management as well as in the pharmaceutical and cosmetic industry; there are already products based on its active substances on the market. This review focuses on the overall evaluation of TTO in terms of effectiveness and safety as a biopesticide for the first time. The collected data can be an added value for further evaluation of TTO in terms of the authorization extension as a fungicide in 2026.
Assuntos
Praguicidas , Óleo de Melaleuca , Óleo de Melaleuca/química , Praguicidas/farmacologia , Agentes de Controle Biológico/farmacologia , HumanosRESUMO
Tea tree extract, containing antioxidant constituents α-terpineol, terpinen-4-ol, and α-terpinene, has a wide range of applications in the cosmetic, food, and pharmaceutical industries. In this study, tea tree extract showed an anticorrosive effect under 1 M HCl solution on mild steel (MS) and 304 stainless steel (STS). Uniform corrosion for MS and pitting corrosion for STS at 298 K were retarded, with inhibition efficiencies of 77% and 86%, respectively. The inhibition of uniform and pitting corrosion was confirmed by scanning electron microscopy and laser scanning confocal microscopy in terms of surface roughness and pitting morphologies. The most effective constituent contributing to the inhibitory performance of tea tree extract was revealed to be α-terpineol, with an inhibition efficiency of 83%. The adsorption of tea tree extract was confirmed by surface characterization analysis using Fourier transform infrared spectroscopy, Raman spectroscopy, and Electrochemical impedance spectroscopy. Interestingly, G- and D-peaks of Raman spectra were detected from the inhibited steels, and this finding is the first example in the corrosion inhibition field. The anticorrosion mechanism can be explained by the formation of organic-Fe complexes on the corroded steel surface via electron donor and acceptor interactions in the presence of an oxygen atom of the hydroxyl group or ether of organic inhibitors.