Extended X-ray absorption fine structure and nuclear resonance vibrational spectroscopy reveal that NifB-co, a FeMo-co precursor, comprises a 6Fe core with an interstitial light atom.

George, Simon J; Igarashi, Robert Y; Xiao, Yuming; Hernandez, Jose A; Demuez, Marie; Zhao, Dehua; Yoda, Yoshitaka; Ludden, Paul W; Rubio, Luis M; Cramer, Stephen P

George, Simon J; Igarashi, Robert Y; Xiao, Yuming; Hernandez, Jose A; Demuez, Marie; Zhao, Dehua; Yoda, Yoshitaka; Ludden, Paul W; Rubio, Luis M; Cramer, Stephen P.

Affiliation

George SJ; Advanced Biological and Environmental X-ray Facility, Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.

J Am Chem Soc ; 130(17): 5673-80, 2008 Apr 30.

Article in En | MEDLINE | ID: mdl-18386899

Subject(s)

Iron Compounds/chemistry; Molybdoferredoxin/chemistry; X-Rays; Absorption; Carbon/chemistry; Electron Spin Resonance Spectroscopy/methods; Iron Compounds/metabolism; Molecular Structure; Molybdoferredoxin/metabolism; Nitrogen/chemistry; Oxygen/chemistry

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: X-Rays / Iron Compounds / Molybdoferredoxin Language: En Journal: J Am Chem Soc Year: 2008 Type: Article Affiliation country: United States

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