Structural characterization of CO-inhibited Mo-nitrogenase by combined application of nuclear resonance vibrational spectroscopy, extended X-ray absorption fine structure, and density functional theory: new insights into the effects of CO binding and the role of the interstitial atom.

Scott, Aubrey D; Pelmenschikov, Vladimir; Guo, Yisong; Yan, Lifen; Wang, Hongxin; George, Simon J; Dapper, Christie H; Newton, William E; Yoda, Yoshitaka; Tanaka, Yoshihito; Cramer, Stephen P

Scott, Aubrey D; Pelmenschikov, Vladimir; Guo, Yisong; Yan, Lifen; Wang, Hongxin; George, Simon J; Dapper, Christie H; Newton, William E; Yoda, Yoshitaka; Tanaka, Yoshihito; Cramer, Stephen P.

Affiliation

Scott AD; Institut für Chemie, Technische Universität Berlin , 10623 Berlin, Germany.

J Am Chem Soc ; 136(45): 15942-54, 2014 Nov 12.

Article in En | MEDLINE | ID: mdl-25275608

Subject(s)

Carbon Monoxide/chemistry; Carbon Monoxide/pharmacology; Enzyme Inhibitors/chemistry; Enzyme Inhibitors/pharmacology; Nitrogenase/antagonists & inhibitors; Nitrogenase/metabolism; Quantum Theory; Azotobacter vinelandii/enzymology; Carbon Monoxide/metabolism; Enzyme Inhibitors/metabolism; Magnetic Resonance Spectroscopy; Models, Molecular; Molybdoferredoxin/metabolism; Mutation; Nitrogenase/chemistry; Nitrogenase/genetics; Protein Conformation; Spectroscopy, Fourier Transform Infrared; X-Ray Absorption Spectroscopy

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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Quantum Theory / Carbon Monoxide / Enzyme Inhibitors / Nitrogenase Language: En Journal: J Am Chem Soc Year: 2014 Type: Article Affiliation country: Germany

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