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UV light-mediated difunctionalization of alkenes with CF3SO2Na: synthesis of trifluoromethyl phenanthrene and anthrone derivatives.
Li, Bing; Fan, Dan; Yang, Chao; Xia, Wujiong.
Affiliation
  • Li B; State Key Lab of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150080, China. xiawj@hit.edu.cn.
Org Biomol Chem ; 14(23): 5293-7, 2016 Jun 21.
Article in En | MEDLINE | ID: mdl-27206267
ABSTRACT
A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp(3)-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2016 Type: Article Affiliation country: China
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Journal subject: BIOQUIMICA / QUIMICA Year: 2016 Type: Article Affiliation country: China