A Convenient One-Pot Synthesis of a Sterically Demanding Aniline from Aryllithium Using Trimethylsilyl Azide, Conversion to <i>ß</i>-Diketimines and Synthesis of a <i>ß</i>-Diketiminate Magnesium Hydride Complex.

Demidov, Nikita; Grebogi, Mateus; Bourne, Connor; McKay, Aidan P; Cordes, David B; Stasch, Andreas

A Convenient One-Pot Synthesis of a Sterically Demanding Aniline from Aryllithium Using Trimethylsilyl Azide, Conversion to ß-Diketimines and Synthesis of a ß-Diketiminate Magnesium Hydride Complex.

Demidov, Nikita; Grebogi, Mateus; Bourne, Connor; McKay, Aidan P; Cordes, David B; Stasch, Andreas.

Affiliation

Demidov N; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.
Grebogi M; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.
Bourne C; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.
McKay AP; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.
Cordes DB; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.
Stasch A; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UK.

Molecules ; 28(22)2023 Nov 13.

Article in En | MEDLINE | ID: mdl-38005290

Key words

aniline synthesis; azides; magnesium hydride; metal-halogen exchange; organolithium reagents; sterically demanding N-ligands; terphenyl ligands; triazenes; ß-diketiminates

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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Molecules Journal subject: BIOLOGIA Year: 2023 Type: Article Affiliation country: United kingdom

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