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Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution.
Cirri, Damiano; Marzo, Tiziano; Mastrorilli, Piero; Petrelli, Valentina; Todisco, Stefano; De Giglio, Elvira; Gellini, Cristina; Ricci, Marilena; Pratesi, Alessandro; Messori, Luigi.
Affiliation
  • Cirri D; Department of Chemistry and Industrial Chemistry, University of Pisa, Via G. Moruzzi 13, 56124 Pisa, Italy.
  • Marzo T; Department of Pharmacy, University of Pisa, Via Bonanno Pisano 6, 56126 Pisa, Italy.
  • Mastrorilli P; Department of Civil, Environmental, Land, Building and Chemical Engineering (DICATECh), Polytechnic University of Bari, Via Orabona 4, 70125 Bari, Italy.
  • Petrelli V; Department of Civil, Environmental, Land, Building and Chemical Engineering (DICATECh), Polytechnic University of Bari, Via Orabona 4, 70125 Bari, Italy.
  • Todisco S; Department of Civil, Environmental, Land, Building and Chemical Engineering (DICATECh), Polytechnic University of Bari, Via Orabona 4, 70125 Bari, Italy.
  • De Giglio E; Department of Chemistry, University of Bari "Aldo Moro", Via Orabona 4, 70125 Bari, Italy.
  • Gellini C; Department of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.
  • Ricci M; Department of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.
  • Pratesi A; Department of Chemistry and Industrial Chemistry, University of Pisa, Via G. Moruzzi 13, 56124 Pisa, Italy.
  • Messori L; Department of Chemistry "Ugo Schiff", University of Florence, Via della Lastruccia 3-13, 50019 Sesto Fiorentino, Italy.
Int J Mol Sci ; 25(13)2024 Jul 05.
Article in En | MEDLINE | ID: mdl-39000514
ABSTRACT
The peculiar behavior of arsenoplatin-1, ([Pt(µ-NHC(CH3)O)2ClAs(OH)2], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named "AsPt blue". A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Oxidation-Reduction Language: En Journal: Int J Mol Sci Year: 2024 Type: Article Affiliation country: Italy
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Full text: 1 Collection: 01-internacional Database: MEDLINE Main subject: Oxidation-Reduction Language: En Journal: Int J Mol Sci Year: 2024 Type: Article Affiliation country: Italy