Synthesis of pterocellin A.
Org Lett
; 8(12): 2651-2, 2006 Jun 08.
Article
en En
| MEDLINE
| ID: mdl-16737336
ABSTRACT
The first total synthesis of pterocellin A (1) was achieved in 10 linear steps from commercially available kojic acid (6) and 2-bromo-3-pyridinol (11) in a convergent sequence. The key constructive steps are a directed lithiation to couple two pyridines and an intramolecular nucleophilic aromatic substitution to form 1. [structure see text]
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Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Alcaloides
/
Compuestos Heterocíclicos con 3 Anillos
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2006
Tipo del documento:
Article
País de afiliación:
Estados Unidos