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catena-Poly[[bis(nitrato-kappa(2)O,O')copper(II)]-mu-propane-1,3-diylbis(diphenylphosphine oxide)-kappa(2)O:O'].
Platt, Andrew W G; Lees, Anthony M J.
Afiliación
  • Platt AW; Faculty of Sciences, Staffordshire University, College Road, Stoke-On-Trent ST4 2DE, England.
Acta Crystallogr C ; 63(Pt 10): m433-5, 2007 Oct.
Article en En | MEDLINE | ID: mdl-17917210
ABSTRACT
The structure of the title complex, [Cu(NO(3))(2)(C(27)H(26)O(2)P(2))](n), consists of polymeric chains formed by propane-1,3-diylbis(diphenylphosphine oxide) ligands bridging between metal centres. The Cu atom lies on a twofold rotation axis and a further symmetry centre bisects the bridging bisphosphine dioxide ligand. The CuO(6) coordination geometry is a distorted octahedron, with the bidentate chelating nitrate groups adopting a cis configuration.
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Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Año: 2007 Tipo del documento: Article País de afiliación: Reino Unido
Buscar en Google
Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr C Año: 2007 Tipo del documento: Article País de afiliación: Reino Unido