Preparation of Pd-based metal monolithic catalysts and a study of their performance in the catalytic combustion of methane.
ChemSusChem
; 1(4): 311-9, 2008.
Article
en En
| MEDLINE
| ID: mdl-18605096
ABSTRACT
A series of Pd/SBA-15/Al2O3/FeCrAl and Pd/5 wt% Ce(1-x)Zr(x)O2/SBA-15/Al2O3/FeCrAl (x = 0-1) metal monolithic catalysts were prepared and characterized by various techniques. The catalytic activity and the stability of the catalysts for methane combustion were evaluated. All the catalysts retain the SBA-15 mesoporous structure, with PdO being confined in its channels. The results show that the addition of Ce(1-x)Zr(x)O2 as promoters can improve the activity and stability of the catalysts. The stabilities of the metal monolithic catalysts are much better than those of Pd/ SBA-15 particle catalysts. The catalyst with ZrO2 as promoter exhibits the best activity and stability (T90= 395 degrees C), and the conversion of methane remains constant during the 700 h test.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Paladio
/
Metano
Idioma:
En
Revista:
ChemSusChem
Asunto de la revista:
QUIMICA
/
TOXICOLOGIA
Año:
2008
Tipo del documento:
Article
País de afiliación:
China