Back-trajectory analysis and source-receptor relationships: particulate matter and nitrogen isotopic composition in rainwater.

ABSTRACT

The southeastern portion of North Carolina features a dense crop and animal agricultural region; previous research suggests that this agricultural presence emits a significant portion of the state's nitrogen (i.e., oxides of nitrogen and ammonia) emissions. These findings indicate that transporting air over this region can affect nitrogen concentrations in precipitation at sites as far as 50 mi away. The study combined nitrate nitrogen isotope data with back-trajectory analysis to examine the relationship between regional nitrogen emission estimates independent of pollutant concentration information. In 2004, the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model was used to determine potential sources of nitrogen in rainwater collected at an urban receptor site in Raleigh, NC. The delta 15N isotope ratio signatures of each sample were used to further differentiate between sources of the rainwater nitrate. This study examined the importance of pollution sources, including animal agricultural activity, and meteorology on rainfall chemistry as well as the implications in fine particulate matter (PM2.5) formation. Samples that transited the dense crop and animal (swine) agricultural region of east-southeastern North Carolina (i.e., the source region) had lower delta 15N isotope ratios in the nitrate ion (average = -2.1 +/- 1.7 per thousand) than those from a counterpart nonagricultural region (average = 0.1 +/- 3 per thousand.) An increase in PM2.5 concentrations in the urban receptor site (yearly average = 15.1 +/- 5.8 microg/m3) was also found to correspond to air transport over the dense agricultural region relative to air that was not subjected to such transport (yearly average = 11.7 +/- 5.8 microg/m3).