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Rh(NHC)-catalyzed direct and selective arylation of quinolines at the 8-position.
Kwak, Jaesung; Kim, Min; Chang, Sukbok.
Afiliación
  • Kwak J; Department of Chemistry and Molecular Level Interface Research Center, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea.
J Am Chem Soc ; 133(11): 3780-3, 2011 Mar 23.
Article en En | MEDLINE | ID: mdl-21355550
ABSTRACT
A new catalytic protocol for the regioselective direct arylation of quinoline derivatives at the 8-position has been developed. The reaction is catalyzed by a Rh(NHC) system, and the choice of the NHC ligand was most important for achieving high reactivity and selectivity.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2011 Tipo del documento: Article

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2011 Tipo del documento: Article