1,3-Bis(4-tert-butyl-benz-yl)-4,5-dihydro-imidazolium chloride monohydrate.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 2): o310-1, 2009 Jan 14.
Article
en En
| MEDLINE
| ID: mdl-21581919
In the title compound, C(25)H(35)N(2) (+)·Cl(-)·H(2)O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N-C-N carbon and the opposite C-C bond. The N-C-N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714â
(8) and 0.286â
(8). In the crystal, O-Hâ¯Cl and C-Hâ¯O hydrogen bonds help to establish the packing.
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01-internacional
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En
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Acta Crystallogr Sect E Struct Rep Online
Año:
2009
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Article