Bis[µ-2-(2-naphth-oxy)acetato]bis-{aqua[2-(2-naphth-oxy)acetato]zinc(II)}.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 5): m540, 2009 Apr 22.
Article
en En
| MEDLINE
| ID: mdl-21583777
ABSTRACT
The title binuclear Zn(II) compound, [Zn(2)(C(12)H(9)O(3))(4)(H(2)O)(2)], is centrosymmetric. Each Zn atom is coordinated by two bridging 2-naphthoxyacetate anions, one terminal 2-naphth-oxy-acetate anion and one water mol-ecule in a distorted ZnO(4) tetra-hedral geometry. The naphthalene system of the bridging ligand is nearly perpendicular to the naphthalene of the terminal ligand, with a dihedral angle of 78.26â
(6)°. Within the binuclear mol-ecule the Znâ¯Zn separation is 3.815â
(5)â
Å. In the crystal structure, inter-molecular O-Hâ¯O hydrogen bonding between the water mol-ecule and carboxyl-ate groups helps to stabilize the crystal structure.
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Colección:
01-internacional
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MEDLINE
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En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2009
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Article