(N,N-Dimethyl-formamide-κO)bis-(3-hy-droxy-picolinato-κN,O)phenyl-bis-muth(III).
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 12): m1547-8, 2010 Nov 13.
Article
en En
| MEDLINE
| ID: mdl-21589241
ABSTRACT
The title organometallic complex, [Bi(C(6)H(5))(C(6)H(4)NO(3))(2)(C(3)H(7)NO)], features a Bi(III) atom in a distorted pentagonal-pyramidal coordination by two N,O-donating bidentate 3-hy-droxy-picolinate (3-hpic) ligands, one monodentate dimethyl-formamide (dmf) mol-ecule and one phenyl ring. The C atom of the aryl ligand occupies the apical position of the BiCN(2)O(3) coordination polyhedron, while the equatorial plane is formed by one O atom of the dmf ligand and two sets of N and O atoms from the chelating 3-hpic ligands. Inter-molecular secondary Biâ¯O [3.485â
(3)â
Å] and O-Hâ¯O hydrogen-bonding inter-actions connect the complexes into a three-dimensional network. Intramolecular O-Hâ¯O hydrogen bonds are also observed.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Año:
2010
Tipo del documento:
Article
País de afiliación:
Estados Unidos