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Palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides.
Liu, Yan-Yun; Yang, Xu-Heng; Huang, Xiao-Cheng; Wei, Wen-Ting; Song, Ren-Jie; Li, Jin-Heng.
Afiliación
  • Liu YY; State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
J Org Chem ; 78(20): 10421-6, 2013 Oct 18.
Article en En | MEDLINE | ID: mdl-24053535
A novel palladium-catalyzed methylation protocol for the synthesis of methyl-functionalized internal alkynes has been established. This methylation method is achieved through a C(sp)-C(sp(3)) bond formation process and represents a new synthetic application of sulfonium ylides.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Paladio / Compuestos de Sulfonio / Alquinos Idioma: En Revista: J Org Chem Año: 2013 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Paladio / Compuestos de Sulfonio / Alquinos Idioma: En Revista: J Org Chem Año: 2013 Tipo del documento: Article País de afiliación: China