A novel intermolecular synthesis of γ-lactones via visible-light photoredox catalysis.
Org Lett
; 15(23): 6054-7, 2013 Dec 06.
Article
en En
| MEDLINE
| ID: mdl-24215594
ABSTRACT
Direct γ-lactone formation via visible-light photoredox catalysis has been achieved efficiently including hydroxylalkylation of aromatic alkenes and transesterification. The present photocatalytic protocol has good regioselectivity and substrate compatibility, affording a novel way to intermolecular γ-lactone synthesis by the reaction of styrenes with α-bromo esters in the absence of any external oxidants.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Alquenos
/
Hidrocarburos Bromados
/
Lactonas
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2013
Tipo del documento:
Article