Aerobic oxidation of alcohols and the synthesis of benzoxazoles catalyzed by a cuprocupric coordination polymer (Cu(+)-CP) assisted by TEMPO.
Inorg Chem
; 54(5): 2088-90, 2015 Mar 02.
Article
en En
| MEDLINE
| ID: mdl-25689139
A Cu(+)-CP based on the tetranuclear unit {[(HSQPA)2Cu4(bipy)4]·2H2O}n·2nH2O has been constructed through Cu(2+) salt, 2-(sulfonylquinlium-8-yloxy)phthalic acid (H3SQPA), and 4,4'-bipyridine (bipy). This Cu(+)-CP combined with 2,2,6,6-tetramethylpiperidine-1-oxyl as the cocatalyst is an effective catalyst for aerobic oxidation of alcohols and the synthesis of benzoxazoles and can be recycled at least four times without losing its catalytic activity.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
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Polímeros
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Benzoxazoles
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Cobre
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Óxidos N-Cíclicos
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Alcoholes
Idioma:
En
Revista:
Inorg Chem
Año:
2015
Tipo del documento:
Article
País de afiliación:
China