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Ammonium Iodide Induced Nonradical Regioselective Sulfenylation of Flavones via a C-H Functionalization Process.
Zhao, Wannian; Xie, Ping; Bian, Zhaogang; Zhou, Aihua; Ge, Haibo; Zhang, Min; Ding, Yingcai; Zheng, Lian.
Afiliación
  • Zhao W; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Xie P; Scientific Information Research Institute, Jiangsu University (Library) , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Bian Z; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Zhou A; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Ge H; Department of Chemistry and Chemical Biology, Indiana University Purdue University Indianapolis , Indianapolis, Indiana 46202, United States.
  • Zhang M; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Ding Y; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
  • Zheng L; Pharmacy School, Jiangsu University , Xuefu Road 301, Zhenjiang City, Jiangsu 212013, China.
J Org Chem ; 80(18): 9167-75, 2015 Sep 18.
Article en En | MEDLINE | ID: mdl-26291122
ABSTRACT
A novel and highly regioselective ammonium iodide-induced nonradical sulfenylation method for the construction of a C-S bond was developed via C-H functionalization. With DMSO or R(1)SO2NHNH2 as a sulfenylating agent, MeS- and R(1)S-substituted flavone derivatives were obtained in good yields. This method enriches current C-S bond formation chemistry, making it a highly valuable and practical method in pharmaceutical industry.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Compuestos de Sulfhidrilo / Flavonas / Compuestos de Amonio Cuaternario Idioma: En Revista: J Org Chem Año: 2015 Tipo del documento: Article País de afiliación: China
Texto completo
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XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Compuestos de Sulfhidrilo / Flavonas / Compuestos de Amonio Cuaternario Idioma: En Revista: J Org Chem Año: 2015 Tipo del documento: Article País de afiliación: China