Ammonium Iodide Induced Nonradical Regioselective Sulfenylation of Flavones via a C-H Functionalization Process.
J Org Chem
; 80(18): 9167-75, 2015 Sep 18.
Article
en En
| MEDLINE
| ID: mdl-26291122
ABSTRACT
A novel and highly regioselective ammonium iodide-induced nonradical sulfenylation method for the construction of a C-S bond was developed via C-H functionalization. With DMSO or R(1)SO2NHNH2 as a sulfenylating agent, MeS- and R(1)S-substituted flavone derivatives were obtained in good yields. This method enriches current C-S bond formation chemistry, making it a highly valuable and practical method in pharmaceutical industry.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Compuestos de Sulfhidrilo
/
Flavonas
/
Compuestos de Amonio Cuaternario
Idioma:
En
Revista:
J Org Chem
Año:
2015
Tipo del documento:
Article
País de afiliación:
China