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Crystal structure of a methimazole-based ionic liquid.
Gaitor, Jamie C; Zayas, Manuel Sanchez; Myrthil, Darrel J; White, Frankie; Hendrich, Jeffrey M; Sykora, Richard E; O'Brien, Richard A; Reilly, John T; Mirjafari, Arsalan.
Afiliación
  • Gaitor JC; Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA.
  • Zayas MS; Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA.
  • Myrthil DJ; Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA.
  • White F; University of South Alabama, Department of Chemistry, Mobile, AL 36688, USA.
  • Hendrich JM; University of South Alabama, Department of Chemistry, Mobile, AL 36688, USA.
  • Sykora RE; University of South Alabama, Department of Chemistry, Mobile, AL 36688, USA.
  • O'Brien RA; University of South Alabama, Department of Chemistry, Mobile, AL 36688, USA.
  • Reilly JT; Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA.
  • Mirjafari A; Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, FL 33965, USA.
Acta Crystallogr E Crystallogr Commun ; 71(Pt 12): o1008-9, 2015 Dec 01.
Article en En | MEDLINE | ID: mdl-26870468
ABSTRACT
The structure of 1-methyl-2-(prop-2-en-1-ylsulfan-yl)-1H-imidazol-3-ium bromide, C7H11N2S(+)·Br(-), has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N-H⋯Br and C-H⋯Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2015 Tipo del documento: Article País de afiliación: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Acta Crystallogr E Crystallogr Commun Año: 2015 Tipo del documento: Article País de afiliación: Estados Unidos