Coordination and supramolecular assembly of {Cd2Ge8V12O48} building block and cucurbit[6] to form rotaxane-shaped hybrids.

Wei, Mei-Jie; Zang, Hong-Ying; Zhou, En-Long; Shao, Kui-Zhan; Song, Bai-Qiao; Wang, Xin-Long; Su, Zhong-Min

Wei, Mei-Jie; Zang, Hong-Ying; Zhou, En-Long; Shao, Kui-Zhan; Song, Bai-Qiao; Wang, Xin-Long; Su, Zhong-Min.

Afiliación

Wei MJ; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Zang HY; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Zhou EL; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Shao KZ; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Song BQ; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Wang XL; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e
Su ZM; Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, P. R. China. zanghy100@nenu.e

Dalton Trans ; 45(12): 4989-92, 2016 Mar 28.

Article en En | MEDLINE | ID: mdl-26934989

ABSTRACT

ABSTRACT

Assembly of cucurbit[6] and a {Cd2Ge8V12O48} cluster produced two rotaxane-shaped and polyrotaxane-shaped solids by changing the ratio of starting precursors in the system. The high oxygen density of the polyoxoanion surface provides active sites to extend a single rotaxane-shaped hybrid 1 to a 1D polyrotaxane-shaped hybrid 2. This construction strategy may afford an entirely new methodology for polyoxometalate-based hybrid chemistry.

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article

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