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Scope and limitations of a DMF bio-alternative within Sonogashira cross-coupling and Cacchi-type annulation.
Wilson, Kirsty L; Kennedy, Alan R; Murray, Jane; Greatrex, Ben; Jamieson, Craig; Watson, Allan J B.
Afiliación
  • Wilson KL; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Thomas Graham Building, 295 Cathedral Street, Glasgow, G1 1XL, UK.
  • Kennedy AR; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Thomas Graham Building, 295 Cathedral Street, Glasgow, G1 1XL, UK.
  • Murray J; Sigma-Aldrich, The Old Brickyard, New Road, Gillingham, Dorset, SP8 4XT, UK.
  • Greatrex B; School of Science and Technology, University of New England, Armidale, Australia, 2351.
  • Jamieson C; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Thomas Graham Building, 295 Cathedral Street, Glasgow, G1 1XL, UK.
  • Watson AJ; Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, Thomas Graham Building, 295 Cathedral Street, Glasgow, G1 1XL, UK.
Beilstein J Org Chem ; 12: 2005-2011, 2016.
Article en En | MEDLINE | ID: mdl-27829904
ABSTRACT
Pd-catalysed C-C bond formation is an essential tool within the pharmaceutical and agrochemical industries. Many of these reactions rely heavily on polar aprotic solvents; however, despite their utility, these solvents are incompatible with the drive towards more sustainable chemical synthesis. Herein, we describe the scope and limitations of an alternative to DMF derived from renewable sources (CyreneTM) in Sonogashira cross-coupling and Cacchi-type annulations.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2016 Tipo del documento: Article País de afiliación: Reino Unido