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Amine-Controlled Divergent Reaction: Iminolactonization and Olefination in the Presence of a Cu(I) Catalyst.
Nishikata, Takashi; Itonaga, Kohei; Yamaguchi, Norihiro; Sumimoto, Michinori.
Afiliación
  • Nishikata T; Graduate School of Science and Engineering, Yamaguchi University , Ube, Yamaguchi 755-8611, Japan.
  • Itonaga K; Graduate School of Science and Engineering, Yamaguchi University , Ube, Yamaguchi 755-8611, Japan.
  • Yamaguchi N; Graduate School of Science and Engineering, Yamaguchi University , Ube, Yamaguchi 755-8611, Japan.
  • Sumimoto M; Graduate School of Science and Engineering, Yamaguchi University , Ube, Yamaguchi 755-8611, Japan.
Org Lett ; 19(10): 2686-2689, 2017 05 19.
Article en En | MEDLINE | ID: mdl-28489397
ABSTRACT
α-Bromoamides and styrenes underwent iminolactonization reactions (carbooxygenation), in which simultaneous C-C and C-O formation occurred in the presence of a copper catalyst with triethylamine as the base. Conversely, olefination reactions occurred in the presence of a Cu catalyst with piperidine as the base. The selectivities in those reactions were very high.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2017 Tipo del documento: Article País de afiliación: Japón
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2017 Tipo del documento: Article País de afiliación: Japón