Thermal decomposition pathways of nitro-functionalized metal-organic frameworks.
Chem Commun (Camb)
; 53(55): 7808-7811, 2017 Jul 06.
Article
en En
| MEDLINE
| ID: mdl-28653067
ABSTRACT
The decomposition behavior of high energy metal-organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2017
Tipo del documento:
Article
País de afiliación:
Estados Unidos