Photoinduced nonlinear optical response in azobenzene-functionalized molecular glass.

ABSTRACT

We show that mexylaminotriazine molecular glass functionalized with the azobenzene derivative Disperse Red 1 shows equally strong second-order nonlinear optical response as well-known polymers with the same photoactive component. Furthermore, even high chromophore loading does not adversely affect the nonlinear response. This suggests that chromophore-chromophore intermolecular interactions do not greatly limit the response of such molecular glasses, which therefore provide an excellent materials platform for nonlinear optical applications.