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Metal-mediated linear self-assembly of porphyrins.
Wytko, J A; Ruppert, R; Jeandon, C; Weiss, J.
Afiliación
  • Wytko JA; Institut de Chimie de Strasbourg, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, France.
Chem Commun (Camb) ; 54(13): 1550-1558, 2018 Feb 08.
Article en En | MEDLINE | ID: mdl-29363684
Porphyrin derivatives are highly relevant to biological processes such as light harvesting and charge separation. Their aromatic electronic structure and their accessible HOMO-LUMO gap render porphyrins highly attractive for the development of opto- and electro-active materials. Due to the often difficult covalent synthesis of multiporphyrins, self-assembly using metal complexation as the driving force can lead to well defined objects exhibiting a controlled morphology, which will be required to analyse and understand the electronic properties of porphyrin wires. This article presents two assembly approaches, namely by peripheral coordination or by binding to a metal ion in the porphyrin core, that are efficient and well designed for future developments requiring interactions with a surface.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Francia

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: Francia