Iodine(III)-mediated halogenations of acyclic monoterpenoids.
Beilstein J Org Chem
; 14: 1103-1111, 2018.
Article
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| MEDLINE
| ID: mdl-29977382
ABSTRACT
Five different halofunctionalizations of acyclic monoterpenoids were performed using a combination of a hypervalent iodine(III) reagent and a halide salt. In this manner, the dibromination, the bromo(trifluoro)acetoxylation, the bromohydroxylation, the iodo(trifluoro)acetoxylation or the ene-type chlorination of the distal trisubstituted double bond occurred with excellent selectivity and moderate to good yields.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Beilstein J Org Chem
Año:
2018
Tipo del documento:
Article
País de afiliación:
Francia