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A neptunium(v)-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [c2]daisy chain unit.
Mei, Lei; Xu, Chao; Wu, Qun-Yan; Hu, Kong-Qiu; Yuan, Li-Yong; Chen, Jing; Xiao, Cheng-Liang; Wang, Shu-Ao; Chai, Zhi-Fang; Shi, Wei-Qun.
Afiliación
  • Mei L; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
  • Xu C; Nuclear Chemistry and Chemical Engineering Division, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China.
  • Wu QY; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
  • Hu KQ; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
  • Yuan LY; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
  • Chen J; Nuclear Chemistry and Chemical Engineering Division, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China.
  • Xiao CL; School of Radiological & Interdisciplinary Sciences, Soochow University, Suzhou, 215123, P. R. China.
  • Wang SA; School of Radiological & Interdisciplinary Sciences, Soochow University, Suzhou, 215123, P. R. China.
  • Chai ZF; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn and School of Radiological & Interdisciplinary Sciences, Soochow University, Suzhou, 215123, P. R. China.
  • Shi WQ; Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
Chem Commun (Camb) ; 54(62): 8645-8648, 2018 Aug 11.
Article en En | MEDLINE | ID: mdl-30022209
ABSTRACT
As an extension of actinide-rotaxane complexes from uranium to transuranium, we report the first crystal structure of a neptunium-rotaxane complex, NRCP-1, in which an interwoven neptunium(v)-rotaxane coordination network incorporating a mechanically-interlocked [c2]daisy chain unit is promoted via the simultaneous coordination of cucurbituril (CB6) and axle molecules in [2]pseudorotaxane to NpV.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Neptunio / Uranio / Rotaxanos / Complejos de Coordinación Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: China
Texto completo
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XML
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Neptunio / Uranio / Rotaxanos / Complejos de Coordinación Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2018 Tipo del documento: Article País de afiliación: China