Synthesis of cobalt-based magnetic nanoporous carbon core-shell molecularly imprinted polymers for the solid-phase extraction of phthalate plasticizers in edible oil.
Anal Bioanal Chem
; 410(26): 6943-6954, 2018 Oct.
Article
en En
| MEDLINE
| ID: mdl-30128807
ABSTRACT
In this work, cobalt magnetic nanoporous carbon (Co-MNPC) is employed as an alternative to intensively used Fe3O4 cores for the preparation of magnetic molecularly imprinted polymers (Co-MNPC@MIPs) for the first time. Co-MNPC was prepared by one-step carbonization of Zeolitic Imidazolate Framework-67 (ZIF-67). Compared with the traditional Fe3O4 core, Co-MNPC showed a high specific surface area and large pore volumes. The prepared adsorbents, which could be rapidly collected from a matrix by external magnetic field, were applied for solid-phase extraction of phthalate plasticizers in edible oil. Several requisite extraction parameters were optimized to achieve desired extraction performance. Under the optimum extraction conditions, Co-MNPC@MIPs displayed better performance than commercialized columns. An analysis method based on Co-MNPC@MIPs coupled with gas chromatography (GC) was established. The linear range was 1-150 µg mL-1, and the detection limit range was 0.010-0.025 µg mL-1. The spiked recovery rate of the five phthalate plasticizers was 81.6-102.2%, with a relative standard deviation of 3.25-12.02%. Finally, the proposed method showed good feasibility for phthalate plasticizer extraction from edible oil.
Palabras clave
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Plastificantes
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Polímeros
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Aceites de Plantas
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Carbono
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Cobalto
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Extracción en Fase Sólida
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Nanopartículas
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Impresión Molecular
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Magnetismo
Idioma:
En
Revista:
Anal Bioanal Chem
Año:
2018
Tipo del documento:
Article
País de afiliación:
China