Self-assembly of sugar based glyco-lipids: Gelation studies of partially protected d-glucose derivatives.

A series of sugar-based glycolipid derivatives were prepared by N-glycosylamines, and their organogelation property has been analyzed. We have observed the efficient gelation for some of the anilines substituted glycolipids derivatives in different aromatic and aliphatic solvents. It was found that the gelation occurred predominantly in aliphatic solvents with CGC of 0.8% (w/v) attributed to the presence of long alkyl chain in the glycolipids. The structural and morphological properties of the xerogels were investigated by NMR, powder XRD, and FE-SEM respectively. Furthermore, the thermal stability was analyzed by DSC.