C-H and C-F Bond Activation Reactions of Fluorinated Propenes at Rhodium: Distinctive Reactivity of the Refrigerant HFO-1234yf.
Angew Chem Int Ed Engl
; 58(31): 10688-10692, 2019 Jul 29.
Article
en En
| MEDLINE
| ID: mdl-31102565
ABSTRACT
The reaction of [Rh(H)(PEt3 )3 ] (1) with the refrigerant HFO-1234yf (2,3,3,3-tetrafluoropropene) affords an efficient route to obtain [Rh(F)(PEt3 )3 ] (3) by C-F bond activation. Catalytic hydrodefluorinations were achieved in the presence of the silane HSiPh3 . In the presence of a fluorosilane, 3 provides a C-H bond activation followed by a 1,2-fluorine shift to produce [Rh{(E)-C(CF3 )=CHF}(PEt3 )3 ] (4). Similar rearrangements of HFO-1234yf were observed at [Rh(E)(PEt3 )3 ] [E=Bpin (6), C7 D7 (8), Me (9)]. The ability to favor C-H bond activation using 3 and fluorosilane is also demonstrated with 3,3,3-trifluoropropene. Studies are supported by DFT calculations.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2019
Tipo del documento:
Article
País de afiliación:
Alemania