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Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions.
Krappitz, Tim; Jovic, Kristina; Feist, Florian; Frisch, Hendrik; Rigoglioso, Vincent P; Blinco, James P; Boydston, Andrew J; Barner-Kowollik, Christopher.
Afiliación
  • Krappitz T; School of Chemistry, Physics and Mechanical Engineering , Queensland University of Technology (QUT) , 2 George Street , Brisbane , QLD 4000 , Australia.
  • Jovic K; School of Chemistry, Physics and Mechanical Engineering , Queensland University of Technology (QUT) , 2 George Street , Brisbane , QLD 4000 , Australia.
  • Feist F; School of Chemistry, Physics and Mechanical Engineering , Queensland University of Technology (QUT) , 2 George Street , Brisbane , QLD 4000 , Australia.
  • Frisch H; Max Planck Institute for Polymer Research , Ackermannweg 10 , 55128 Mainz , Germany.
  • Rigoglioso VP; School of Chemistry, Physics and Mechanical Engineering , Queensland University of Technology (QUT) , 2 George Street , Brisbane , QLD 4000 , Australia.
  • Blinco JP; Department of Chemistry , University of Wisconsin-Madison , 1101 University Avenue , Madison , Wisconsin 53706 , United States.
  • Boydston AJ; School of Chemistry, Physics and Mechanical Engineering , Queensland University of Technology (QUT) , 2 George Street , Brisbane , QLD 4000 , Australia.
  • Barner-Kowollik C; Department of Chemistry , University of Wisconsin-Madison , 1101 University Avenue , Madison , Wisconsin 53706 , United States.
J Am Chem Soc ; 141(42): 16605-16609, 2019 10 23.
Article en En | MEDLINE | ID: mdl-31592659
We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Australia
Texto completo
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XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: J Am Chem Soc Año: 2019 Tipo del documento: Article País de afiliación: Australia