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Understanding the unorthodox stabilization of liquid phase exfoliated molybdenum disulfide (MoS2) in water medium.
Rodriguez, Camila L C; Muñoz, Pablo A R; Donato, Katarzyna Z; Seixas, Leandro; Donato, Ricardo K; Fechine, Guilhermino J M.
Afiliación
  • Rodriguez CLC; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br.
  • Muñoz PAR; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br.
  • Donato KZ; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br and Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2
  • Seixas L; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br.
  • Donato RK; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br and Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2
  • Fechine GJM; MackGraphe - Mackenzie Institute for Research in Graphene and Nanotechnologies, Mackenzie Presbyterian University, Rua da Consolação, 896, São Paulo SP 01302-907, Brazil. guilherminojmf@mackenzie.br.
Phys Chem Chem Phys ; 22(3): 1457-1465, 2020 Jan 21.
Article en En | MEDLINE | ID: mdl-31859694
ABSTRACT
Molybdenum disulfide is a highly esteemed 2D material with interesting applications in nanoelectronics, composites, biotechnology and beyond. Its production through liquid-phase exfoliation in H2O is low-cost and eco-friendly. Herein, we present a detailed experimental and theoretical investigation seeking to explain the peculiar stability of MoS2 in H2O medium. By combining different microscopic (SEM, AFM and OM), spectrometric (Raman, UV-vis and AFM-FTIR), scattering (DLS) and ab initio simulation techniques, an edge-functionalization hypothesis for the excellent solvent properties of water for producing few-layer MoS2 has been demonstrated.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Brasil

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2020 Tipo del documento: Article País de afiliación: Brasil