Colloidal Stabilization of Sodium Dilauraminocystine for Selective Nanoparticle-Nanoparticle Interactions: Their Screening and Extraction by Iron Oxide Magnetic Nanoparticles.

ABSTRACT

Nanoparticle-nanoparticle (NP-NP) interactions between Au and Ag NPs were studied by using sodium dilauraminocystine (SDLC)- and Gemini surfactant-stabilized NPs to demonstrate the unique NP surface adsorption behavior of SDLC in controlling and mimicking such interactions in complex mixtures. They were significantly affected by the spacer as well as the polymeric nature of the head group of Gemini surfactants. A longer spacer impeded while a polymeric head group facilitated the interactions. The Au-Ag NPs interactions in an aqueous phase were also controlled by placing surface-active magnetic NPs at an aqueous-air interface, which interacted with either or both kinds of interacting NPs in an aqueous phase and reduced their ability to interact with each other. On the other hand, water-soluble zwitterionic magnetic NPs proved to be excellent extractants of both Au and Ag NPs from the aqueous phase. Extraction efficiency depended on the strength of interactions between the water-soluble magnetic NPs and aqueous-solubilized Au and/or Ag NPs.