Superhydrophilic and Photothermal Fe-TCPP Nanofibrous Membrane for Efficient Oil-in-Water Nanoemulsion Separation.
Langmuir
; 37(44): 12981-12989, 2021 Nov 09.
Article
en En
| MEDLINE
| ID: mdl-34711051
ABSTRACT
Separation and purification of surfactant-stabilized oil-in-water nanoemulsions is a great environmental challenge. Membrane-based separation strategies are more effective over conventional methods in the treatment of nanoemulsion waste water. In this paper, we construct a superhydrophilic membrane by coating a thin photothermal-responsive iron tetrakis(4-carboxyphenyl)porphyrin (Fe-TCPP) nanofibrous metal organic framework (MOF) selective layer on a macroporous polyethersulfone membrane. The as-prepared membrane exhibits high separation performance of oil-in-water nanoemulsions with permeance of 46.4 L·m-2·h-1·bar-1 and separation efficiency of 99%. It also demonstrates nice anti-oil/ionic-fouling property, good recyclability, and desirable stability. The high separation performance is accredited to the superhydrophilicity, highly charged surface, and nanometer pore sizes of the Fe-TCPP nanofibrous membrane. Due to the unique photothermal property of Fe-TCPP nanofibers, the permeance can be enhanced more than 50% by visible light without deteriorating the rejection. This photo-stimuli MOF-based thin-layer membrane offers great potential for the generation of point-of-use water treatment devices.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Langmuir
Asunto de la revista:
QUIMICA
Año:
2021
Tipo del documento:
Article