Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis.
Chem Rev
; 122(2): 1485-1542, 2022 01 26.
Article
en En
| MEDLINE
| ID: mdl-34793128
ABSTRACT
The merger of photoredox catalysis with transition metal catalysis, termed metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past decade. Metallaphotoredox catalysis has combined the unparalleled capacity of transition metal catalysis for bond formation with the broad utility of photoinduced electron- and energy-transfer processes. Photocatalytic substrate activation has allowed the engagement of simple starting materials in metal-mediated bond-forming processes. Moreover, electron or energy transfer directly with key organometallic intermediates has provided novel activation modes entirely complementary to traditional catalytic platforms. This Review details and contextualizes the advancements in molecule construction brought forth by metallaphotocatalysis.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Elementos de Transición
/
Electrones
Idioma:
En
Revista:
Chem Rev
Año:
2022
Tipo del documento:
Article
País de afiliación:
Estados Unidos