Mid-IR spectroscopy with NIR grating spectrometers.
Opt Express
; 30(4): 5926-5936, 2022 Feb 14.
Article
en En
| MEDLINE
| ID: mdl-35209544
ABSTRACT
Mid-infrared (mid-IR) spectroscopy is a crucial workhorse for a plethora of analytical applications and is suitable for diverse materials, including gases, polymers or biological tissue. However, this technologically significant wavelength regime between 2.5-10 µm suffers from technical limitations primarily related to the large noise in mid-IR detectors and the complexity and cost of bright, broadband mid-IR light sources. Here, using highly non-degenerate, broadband photon pairs from bright spontaneous parametric down-conversion (SPDC) in a nonlinear interferometer, we circumvent these limitations and realise spectroscopy in the mid-IR using only a visible (VIS) solid-state laser and an off-the-shelf, commercial near-infrared (NIR) grating spectrometer. With this proof-of-concept implementation, covering a broad range from 3.2 µm to 4.4 µm we demonstrate short integration times down to 1 s and signal-to-noise ratios above 200 at a spectral resolution from 12 cm-1 down to 1.5 cm-1 for longer integration times. Through the analysis of polymer samples and the ambient CO2 in our laboratory, we highlight the potential of this measurement technique for real-world applications.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Opt Express
Asunto de la revista:
OFTALMOLOGIA
Año:
2022
Tipo del documento:
Article