On-Surface Debromination of C6Br6: C6 Ring versus C6 Chain.
ACS Nano
; 16(4): 6578-6584, 2022 Apr 26.
Article
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| MEDLINE
| ID: mdl-35377612
ABSTRACT
Carbon allotropes comprising sp-hybridized carbon atoms have been investigated for decades for their molecular structure. One of the unsolved mysteries is whether they should take a linear or cyclic configuration in condensed phases due to the lack of atomistic characterizations. Herein, we designed a molecule with a C6 skeleton as a model system to address this issue, which was achieved by eliminating Br atoms from hexabromobenzene (C6Br6) molecule on the Ag(111) substrate via thermal treatment. It is found that the C6 ring intermediate resulting from complete debromination is energetically unstable at room temperature based on theoretical calculations. It subsequently transforms into the C6 polyynic chain via a ring-opening process and ultimately polymerizes into the organometallic polyyne, whose triyne structural unit is revealed by bond-resolved noncontact atomic force microscopy. Theoretical calculations demonstrated an energetically favorable pathway in which the ring-opening process occurs after complete debromination of C6Br6. Our study provides a platform for the synthesis of elusive carbon-rich materials.
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Colección:
01-internacional
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MEDLINE
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En
Revista:
ACS Nano
Año:
2022
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Article