Catalyst- and Oxidizing Reagent-Free Electrochemical Benzylic C(sp3)-H Oxidation of Phenol Derivatives.
J Org Chem
; 87(12): 7806-7817, 2022 Jun 17.
Article
en En
| MEDLINE
| ID: mdl-35648817
ABSTRACT
A site-selective electrochemical approach for the benzylic C(sp3)-H oxidation reaction of phenol derivatives along with hydrogen evolution has been developed. The protocol proceeds in an easily available undivided cell at room temperature under catalyst- and oxidizing reagent-free conditions. The corresponding aryl aldehydes and ketones are obtained in satisfactory yields, and the gram-scale synthesis is easy to be carried out.
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Colección:
01-internacional
Banco de datos:
MEDLINE
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En
Revista:
J Org Chem
Año:
2022
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Article