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Photoredox-Catalyzed Acyl Lactonization of Alkenes with Aldehydes: Synthesis of Acyl Lactones.
Rao, Wei-Hao; Li, Qi; Jiang, Li-Li; Li, Ying-Ge; Xu, Pan; Deng, Xue-Wan; Li, Ming; Zou, Guo-Dong; Cao, Xinhua.
Afiliación
  • Rao WH; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Li Q; Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan 430062, China.
  • Jiang LL; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Li YG; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Xu P; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Deng XW; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Li M; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Zou GD; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
  • Cao X; College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang 464000, China.
J Org Chem ; 87(21): 14194-14207, 2022 11 04.
Article en En | MEDLINE | ID: mdl-36265020
ABSTRACT
An acyl lactonization of alkenes with aldehydes under visible-light photoredox catalysis is described. With the protocol, a broad scope of alkenoic acids and aldehydes could be compatible and good functional group tolerance is obtained. A series of acyl lactones are obtained with isolated yields ranging from 50-95%. Mechanistic studies revealed that the transformation should proceed via a radical chain process.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Aldehídos / Alquenos Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: China
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Aldehídos / Alquenos Idioma: En Revista: J Org Chem Año: 2022 Tipo del documento: Article País de afiliación: China