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Redox-Neutral 1,4-Dicarbonfunctionalization of 1,3-Butadiene by Merging Photoredox and Nickel Catalysis.
Ding, Du; Fan, Lian-Feng; Han, Zhi-Yong; Wang, Pu-Sheng.
Afiliación
  • Ding D; Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
  • Fan LF; Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
  • Han ZY; Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
  • Wang PS; Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China.
Org Lett ; 25(1): 210-214, 2023 01 13.
Article en En | MEDLINE | ID: mdl-36534618
ABSTRACT
The diverse functionalization of 1,3-butadiene provides wide applicability toward the synthesis of abundant and useful allylic compounds. Here, we describe a three-component and redox-neutral assembly of readily available C═X compounds, 1,3-butadiene, and various nucleophiles by merging photoredox and nickel catalysis, enabling the rapid synthesis of structurally diverse homoallyl amines and homoallylic alcohols.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Butadienos / Níquel Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2023 Tipo del documento: Article País de afiliación: China

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Butadienos / Níquel Idioma: En Revista: Org Lett Asunto de la revista: BIOQUIMICA Año: 2023 Tipo del documento: Article País de afiliación: China