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A green chemistry approach for oxidation of alcohols using novel bioactive cobalt composite immobilized on polysulfone fibrous network nanoparticles as a catalyst.
Ramírez-Coronel, Andrés Alexis; Mezan, Salim Oudah; Patra, Indrajit; Sivaraman, Ramaswamy; Riadi, Yassine; Khakberdiev, Shukhrat; Lafta, Holya A; Abosaooda, Munther; Turki Jalil, Abduladheem; Fakri Mustafa, Yasser.
Afiliación
  • Ramírez-Coronel AA; Laboratory of Psychometrics, Comparative Psychology and Ethology (LABPPCE), Health and Behavior Research Group (HBR), Cuenca, Ecuador.
  • Mezan SO; General Directorate of Education in Al-Muthanna Governorate, Ministry of Education, Baghdad, Iraq.
  • Patra I; An Independent Researcher, NIT Durgapur, Durgapur, West Bengal, India.
  • Sivaraman R; Department of Mathematics, Dwaraka Doss Goverdhan Doss Vaishnav College, University of Madras, Chennai, India.
  • Riadi Y; Department of Pharmaceutical Chemistry, College of Pharmacy, Prince Sattam bin Abdulaziz University, Al-Kharj, Saudi Arabia.
  • Khakberdiev S; Head of the Chemistry Department, Jizzakh Polytechnic Institute, Jizzakh, Uzbekistan.
  • Lafta HA; Al-Nisour University College, Baghdad, Iraq.
  • Abosaooda M; College of Pharmacy, The Islamic University, Najaf, Iraq.
  • Turki Jalil A; Medical Laboratories Techniques Department, Al-Mustaqbal University College, Hilla, Babylon, Iraq.
  • Fakri Mustafa Y; Department of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul, Iraq.
Front Chem ; 10: 1015515, 2022.
Article en En | MEDLINE | ID: mdl-36605117
ABSTRACT
In this study, cobalt composite immobilized on polysulfone fibrous network nanoparticles (CCPSF NPs) were synthesized in a controllable and one-step way under microwave-assisted conditions. The structure of CCPSF NPs was characterized by SEM images (for morphology and size distribution), TGA (for thermal stability), BET technique (for the specific surface area), FT-IR spectroscopy (for relation group characterization), and XRD patterns (for crystal size). The oxidation of the primary and secondary alcohols to aldehyde and ketone was investigated using synthesized CCPSF NPs under solvent-free microwave-assisted conditions, and high oxidizing activity was observed. In addition to oxidation properties, the anticancer activity of the synthesized CCPSF NPs in breast cancer was evaluated by the MTT method , and significant results were obtained.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Front Chem Año: 2022 Tipo del documento: Article País de afiliación: Ecuador

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Front Chem Año: 2022 Tipo del documento: Article País de afiliación: Ecuador