Structural Change and Radical Generation of a Cadmium-Based Metal-Organic Framework Induced by an Electric Field.
Inorg Chem
; 62(23): 8784-8788, 2023 Jun 12.
Article
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| MEDLINE
| ID: mdl-37253277
ABSTRACT
Herein we report the structural change and radical generation of a cadmium-based metal-organic framework (Cd-MOF) induced by external electric fields. Under a weaker single electric field, different coordination modes of Cd-L lead to 3D â 2D structural change. Under stronger superposed electric fields, Cd-MOF was excited to produce a stable free radical. This study will provide a new avenue for the controlled assembly of MOFs.
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Colección:
01-internacional
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MEDLINE
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En
Revista:
Inorg Chem
Año:
2023
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Article