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Visible-Light/Nickel-Catalyzed Carboxylation of C(sp2) Bromides via Formate Activation.
Smith, Gavin C; Zhang, Drason H; Zhang, Wanli; Soliven, Abigail H; Wuest, William M.
Afiliación
  • Smith GC; Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
  • Zhang DH; Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
  • Zhang W; Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
  • Soliven AH; Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.
  • Wuest WM; Department of Chemistry, Emory University, Atlanta, Georgia 30322, United States.
J Org Chem ; 88(13): 9565-9568, 2023 Jul 07.
Article en En | MEDLINE | ID: mdl-37319431
ABSTRACT
A new visible-light-driven method for the carboxylation of (hetero)aryl/vinyl bromides has been developed using catalytic 4CzIPN, nickel, phenyl triflimide, and sodium formate as a carboxylation agent. Interestingly, we found catalytic phenyl triflimide plays an essential role in promoting the reaction. While many C(sp2) carboxylation reactions require harsh reagents or gaseous carbon dioxide, we demonstrate the mild and facile construction of carboxylic acids from readily available starting materials.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Bromuros / Níquel Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Bromuros / Níquel Idioma: En Revista: J Org Chem Año: 2023 Tipo del documento: Article País de afiliación: Estados Unidos