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A family of oxychloride amorphous solid electrolytes for long-cycling all-solid-state lithium batteries.
Zhang, Shumin; Zhao, Feipeng; Chen, Jiatang; Fu, Jiamin; Luo, Jing; Alahakoon, Sandamini H; Chang, Lo-Yueh; Feng, Renfei; Shakouri, Mohsen; Liang, Jianwen; Zhao, Yang; Li, Xiaona; He, Le; Huang, Yining; Sham, Tsun-Kong; Sun, Xueliang.
Afiliación
  • Zhang S; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Zhao F; Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada.
  • Chen J; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Fu J; Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada.
  • Luo J; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Alahakoon SH; Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada.
  • Chang LY; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Feng R; Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada.
  • Shakouri M; National Synchrotron Radiation Research Centre, 101 Hsin-Ann Road, Hsinchu, 30076, Taiwan.
  • Liang J; Canadian Light Source Inc., University of Saskatchewan, Saskatoon, Saskatchewan, S7N 2V3, Canada.
  • Zhao Y; Canadian Light Source Inc., University of Saskatchewan, Saskatoon, Saskatchewan, S7N 2V3, Canada.
  • Li X; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • He L; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Huang Y; Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
  • Sham TK; Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou, PR China.
  • Sun X; Department of Chemistry, University of Western Ontario, London, ON, N6A 5B7, Canada.
Nat Commun ; 14(1): 3780, 2023 Jun 24.
Article en En | MEDLINE | ID: mdl-37355635
ABSTRACT
Solid electrolyte is vital to ensure all-solid-state batteries with improved safety, long cyclability, and feasibility at different temperatures. Herein, we report a new family of amorphous solid electrolytes, xLi2O-MCly (M = Ta or Hf, 0.8 ≤ x ≤ 2, y = 5 or 4). xLi2O-MCly amorphous solid electrolytes can achieve desirable ionic conductivities up to 6.6 × 10-3 S cm-1 at 25 °C, which is one of the highest values among all the reported amorphous solid electrolytes and comparable to those of the popular crystalline ones. The mixed-anion structural models of xLi2O-MCly amorphous SEs are well established and correlated to the ionic conductivities. It is found that the oxygen-jointed anion networks with abundant terminal chlorines in xLi2O-MCly amorphous solid electrolytes play an important role for the fast Li-ion conduction. More importantly, all-solid-state batteries using the amorphous solid electrolytes show excellent electrochemical performance at both 25 °C and -10 °C. Long cycle life (more than 2400 times of charging and discharging) can be achieved for all-solid-state batteries using the xLi2O-TaCl5 amorphous solid electrolyte at 400 mA g-1, demonstrating vast application prospects of the oxychloride amorphous solid electrolytes.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Líquidos Corporales / Litio Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2023 Tipo del documento: Article País de afiliación: Canadá
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Líquidos Corporales / Litio Idioma: En Revista: Nat Commun Asunto de la revista: BIOLOGIA / CIENCIA Año: 2023 Tipo del documento: Article País de afiliación: Canadá