Simply accessible platinum(II) complexes enabling alkene hydrosilylation at ppm catalyst loadings.

Maliszewski, Benon P; Casillo, Eleonora; Lambert, Perrine; Nahra, Fady; Cazin, Catherine S J; Nolan, Steven P

Maliszewski, Benon P; Casillo, Eleonora; Lambert, Perrine; Nahra, Fady; Cazin, Catherine S J; Nolan, Steven P.

Afiliación

Maliszewski BP; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium. steven.nolan@ugent.be.
Casillo E; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium. steven.nolan@ugent.be.
Lambert P; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium. steven.nolan@ugent.be.
Nahra F; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium. steven.nolan@ugent.be.
Cazin CSJ; VITO (Flemish Institute for Technological Research), Separation and Conversion Technology, Boeretang 200, Mol 2400, Belgium. fady.nahra@vito.be.
Nolan SP; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium. steven.nolan@ugent.be.

Chem Commun (Camb) ; 59(94): 14017-14020, 2023 Nov 23.

Article en En | MEDLINE | ID: mdl-37942945

ABSTRACT

ABSTRACT

An efficient olefin hydrosilylation protocol utilising Pt(II)-thioether-based pre-catalysts is reported. These simple and readily available complexes exhibit excellent catalytic performance and offer significant advantages over existing alternatives, enabling rapid and high conversions at ppm-level catalyst loadings.

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2023 Tipo del documento: Article País de afiliación: Bélgica

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