Structural tuning of ß-enamino diketones: exploration of solution and crystalline state photochromism.
Front Chem
; 11: 1295347, 2023.
Article
en En
| MEDLINE
| ID: mdl-38025049
ABSTRACT
A library of ß-enamino diketones was prepared via base-mediated, three-component reaction of 4-hydroxycoumarins with various aromatic/aliphatic amines and ß-nitrostyrenes under microwave irradiation conditions to investigate their photochemical properties. Among the prepared compounds, a thiophene derived ß-enamino diketone was found to be light-sensitive and to exhibit unique photochromic behavior, that is, positive photochromism in solution and negative photochromism in crystalline phase. In addition, this prepared photochromic compound was further covalently linked to a structure-related, piezochromic ß-enamino diketone moiety to explore its potential multi-stimuli responsive properties.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Front Chem
Año:
2023
Tipo del documento:
Article
País de afiliación:
Taiwán