Encapsulation of Cu-modified SnO2 yolk-shell in V2O5-amalgamated wrinkled g-C3N4 lamella for boosting antibiotic photodegradation.

ABSTRACT

The remarkable application of tin oxide in various domains is indebted to its photoelectronic merits. However, significant efforts to discover its photocatalytic potential were restricted through arduous challenges, which were the amelioration of light-harvesting and -utilizing. In fact, the uncommon light absorption energy has drawn veil over the brilliance of astounding oxidation potential, which is much more than that of TiO2. Herein, our attention was focused on the taking advantages of self-template structure for simultaneously enjoying the two sides of photoelectronic justification as well as the S-step system for eminent charge dissociation. In this regard, the optimized Cu-modified SnO2 yolk-shell ((5)YS-CuSnO) spheres were engineered through the copper modulation into glycerate-assisted metal-organic structure. As a result, the exceptional light-harvesting was achieved through desirable defects and oxygen vacancy resulted from Cu-doping, and also efficient light-utilization was obtained by the multi-scattering/reflection effect resulted from multi-shell configuration. After the effectual incorporation (40 wt⁒) of (5)YS-CuSnO was encapsulated into the V2O5-decorated wrinkled g-C3N4 lamella (VO-WCN), the dual S-step VO-WCN@(5)YS-CuSnO introduced unprecedented levofloxacin (LFC) decontamination performance, which was kinetically 5.2 and 30.2-times greater than of the (5)YS-CuSnO and bare SnO2 yolk-shell. The conspicuous fulfillment of nanocomposite was manifested in the LFC mineralization, pharmaceutical effluent treatment within 360 min, and successive cycling reactions. The fusion of the extraordinary architecture of YS-CuSnO with S-Step system not only initiates the facile and practical photocatalytic exploitation, but shade light on some undeveloped side of tin oxide.