Construction of composite self-assembly coating based on chitosan for enhancing the flame-retardant and antibacterial performances of cotton fabric.

ABSTRACT

In this work, the step-by-step dip-coating (SBS) method was used to effectively improve the drawback of LBL by reducing the construction of a multilayer polyelectrolyte. Bio-based flame retardants, phytic acid (PA), and chitosan (CS) were further self-assembly on the surface of cotton fabric treated by epichlorohydrin-modified aramid nanofibers (AEP), ionic liquid (IL), and Cu ion. The pure cotton fabric was immersed in each dipping liquid only once, improving fire safety and antibacterial performance. The treated cotton self-extinguished with a 59 mm char length in the vertical flammability test, and the limiting oxygen index (LOI) value increased from 18.5 % to 38.5 %. The result of the cone calorimeter test (CCT) revealed that the fire hazard of flame-retardant cotton noteworthy declined (e.g., ~44.1 % and 55.4 % decline in peak heat release rate (pHRR) and total heat release rate (THR)). Conspicuously, the treated cotton exhibited a remarkably inhibiting effect on E. coli and S. aureus activity. The cotton fabric after flame-retardant finishing exhibited excellent fire safety and antibacterial performance.