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Visible Light Promoted de Mayo Type Reaction of Bicyclo[1.1.0]butanes.
Yang, Chunming; Hu, Minmin; Hu, Chaoqin; Mi, Xueling; Luo, Sanzhong.
Afiliación
  • Yang C; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Hu M; College of Chemistry, Beijing Normal University, Beijing, 1000875, China.
  • Hu C; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
  • Mi X; College of Chemistry, Beijing Normal University, Beijing, 1000875, China.
  • Luo S; Center of Basic Molecular Science, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
Chemistry ; : e202402965, 2024 Aug 22.
Article en En | MEDLINE | ID: mdl-39174490
ABSTRACT
We reported herein a visible light mediated de Mayo-type reaction between 1,3-diketones and BCB. The reaction proceeds through a [2π+2σ] cycloaddition and retro-aldol sequence, producing cis-difunctionalized cyclobutanes in high yields with good regio- and diastereoselectivity.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2024 Tipo del documento: Article País de afiliación: China